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  • 专利说明
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    • 专利摘要:
    1. Suspension for controlling undesirable vegetation, containing an active substance based on pyridazone p (b), dispersant — sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde, stabilizers — silicic acid, and a block copolymer with an average molecular weight of 6500 based on a full-hydroxypropylene block having an average molecular weight of 3250 and symmetrically attached blocks of ethylene oxide and water, characterized in that, in order to increase storage stability, it is as an active substance The formulation contains a mixture of 1-phenyl-4-amino-5-tslor-pyridazone- (6) with 2,3-dichlorallyl ester K, N-diisopropylthiolcarbamic acid in the following ratio of components, wt.%: 1-Phenyl-4-amino -5- chlorine-pyrvdazo n- ((} 2f3-Dichlorallyl 20-50 ester S, N-diisopropyl-thiol-carbamic acid 5-45 Sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde 2-10 Silicon. Eva acid 0.5-5 - copolyner 0.5-5 Water Remaining, and the indicated pyridazone and ether are taken in a mass ratio of 4: 1-1: 2, 2. Suspension to combat n It is desirable vegetation comprising an active substance based on piridazona- (b), a dispersant - sodium salt of a condensation product of phenolsulfonic acid, formaldehyde and yucheviny stabilizers - silicon. acid and a block copolymer with an average molecular weight of 6500 based on a polyoxypropylene block having an average molecular weight of 3250 and symmetrically attached to it ethylene oxide blocks and water, characterized in that, in order to increase storage stability, it is as active substance contains a mixture of 1-phenyl-4-amino-5-chloro-pyridazone- (6) with N, N-diisopropylthiolcarbamic acid 2,3,3-triallyl ester in the following ratio of components,% by weight: 1-Phenyl -4-amino-5- chloro-pyridazone- (6) 32.5
    公开号:SU1215602A3
    申请号:SU802888999
    申请日:1980-03-04
    公开日:1986-02-28
    发明作者:Клойзер Дитер；Виггер Аугуст
    申请人:Басф Аг (Фирма)；
    IPC主号:
    专利说明:

    2,3, Z-Triallyl ester of N, N-flHH3onpo-piltiolcarbamic acid
    The sodium salt of the condensation product of phenol sulfate is green, urea and formaldehyde. Silicic acid
    The specified block copolymer Water


    3, Suspension for controlling undesirable vegetation, containing the active substance based on pyridazone- (b), dispersant — sodium salt of condensation product of phenol-sulfonic acid, urea and formaldehyde, stabilizers — silicic acid, and a block copolymer with an average molecular weight 6500 on the basis of a polyoxypropylene block, having an average molecular weight of 3250 and symmetrically attached blocks of ethylene oxide and water, characterized in that, in order to increase stability during storage, it is contains a mixture of 1-phenyl-4-amino-5-tiur-pyriddzon- (6) with l-ethyl-N-cyclohexylthiolcarbamino bic acid ethyl ester in the following ratio of components, wt.%:
    1-Fensch-1-4-amino-5-chloro-pyridazone- 6 Said thiol carbamate
    Sodium salt of condensation product of phenol-sulfonic acid, urea and formaldehyde Silicic acid Specified block copolymer Water



    moreover, said pyridazone and ether are taken in a mass ratio l: (l, 15-1.54).
    4. Suspension for controlling undesirable vegetation, containing the active substance based on pyridazone- (b), dispersant sodium salt of the condensation product phenol sulfonic acid, urea and formaldehyde, stabilizers - silicic acid and a block copolymer with an average molecular weight of 6500 polyoxyprop gene block having an average molecular weight of 3250 and symmetrically attached blocks of ethylene oxide and water, characterized in that, in order to increase stability during storage, it as an active substance contains a mixture of 1 fenk - amino-5-chloro-pyridazone- (b) with 2-ethyl-6-methyl-N-ethyl-M - (- methyl-2-methoxyethyl-chloroacetanilide in the following ratio of components, wt.%:
    1 -Phenyl-4-amino
    5-chloro-pyridazone- (6 21.6-32.5
    Specified
    chloroacetanilide 18.7-33.3
    Sodium
    va. salt,
    product
    phenolsulfonic acid condensation,
    urea and
    formaldehyde 3, 0-4.5
    Kr €; Poland
    acid1.0-1.5
    The specified block copolymer 1,5-2,3
    WaterEverything,
    moreover, said pyridazone and chloro-acetav: ylide are taken in a mass ratio of 1.73: 1 or 1: 1.54.
    5. Suspension for the control of undesirable vegetation containing the active substance based on pyridazone- (6 dispersant - the sodium salt of the condensation product of phenol sulfonic acid, urea and formaldehyde, stabilizers - silicic acid and a block copolymer with an average molecular weight of 6500 based on polyoxypropylene a block having a mean molecular weight of 3250 and symmetrically attached to the blocks of ethylene oxide, and water is characterized in that, in order to increase stability during storage, it is as an active ingredient; win mixture of 1-phenyl-4-amino-5-bromo-piridazona- (b) from 2.6
    Dinitro-3,4-dimethyl-N- (1-ethyl-n-propyl - aniline in the following ratio of components, wt.%:
    1-Fensch1-4-amino5-bromo-pyridazone- (6) 21.4
    The indicated 2,6-di; nitroaniline21,4
    This invention relates to chemical plant protection products, namely, a stable suspension for controlling undesirable vegetation.
    The purpose of the invention is to increase the stability of the suspension during storage.
    PRI me R 1. A. Predlagae jy (1 option}.
    430 weight.h. (43 wt.%) 1-phenyl-4-amino-5-chloropyridazone- (b), 60 parts by weight (b wt.%) The sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde, 20 parts by weight (2 wt.%) Sinteti-; cic silicic acid and 30 wt. (G May.%) A block copolymer with an average molecular weight of 6500 based on a polyoxypropylene block, which is referred to as the average molecular weight of 3250, and symmetrically attached blocks of ethylene oxide, is stirred and supplemented with water to 1000 ml. The resulting mixture is ground in a mill to the degree of fineness, at which approximately 95 wt.% Particles less than 2 microns.
    To 767 ml of the resulting suspension, containing 330 g of the specified chloropyridazone, 220 g of 2,3-dichlo complex is added, N, M-di-isopropylthiolcarbamic acid rally ester is added to 1000 ml with distilled water and then stirred vigorously until obtain a homogeneous mixture. .
    A suspension is obtained containing, in wt.%: 1-phenyl-4-amino-5-chloropyridazone- (b) 33, N-N-di-isopropylthiol 2,3-dichloroyl-lilyl ester, sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde silicon
    acid
    The specified block copolymer Water
    carbamic acid, 22; sodium salt of the condensation product of phenol-sulfonic acid, urea and formaldehyde 4.6; synthetic acid
    this 1.5 J said block copolymer 2.5) water is 36.6, the mass ratio of said chloropyrzdazone and: thiol carbamate is 1.5: 1, this suspension is converted into 2% aqueous
    a drug that is stored for 6 hours at
    room temperature. In this case, the formation of a 0.08 mp bottom sediment is observed. After additional storage at room temperature
    for 3 months the amount of bottom sediment does not increase. In addition, the 2% aqueous preparation is stored at 50 ° C for 3 months. At this, a formation of 0.08 MP of bottom sediment is observed.
    B. According to the known. Example 1A is repeated, with the difference that 1-phenyl-4-amino-5-chloro-tetra-zone- (B1 and 2,3-dichloroacetic ester of N, N- ..
    Diisopropylthiolcarbamic acid is used in a weight ratio of 1: 2.5. However, after storing the 2% aqueous drug at room temperature for 6 hours
    3 ml of water precipitate is observed, at room temperature for 3 months - ml of bottom sediment and at temperature for 3 months - 8.6 ml of bottom sediment.
    ka
    Example2, A. Suggested (P option).
    Example 1A is repeated with the difference that to 756 ml of an aqueous suspension,
    containing 325 g of 1-phenyl-4-amino-5-chloropyrl-zaszone- (b), 200 g are added
    3
    2,3, 3-triallyl ester of N, N-diisopropylthiol-carboxylic acid and then with distilled water, add up to 1000 MP, and then stir vigorously to obtain a homogeneous mixture. Get a suspension containing wt.%: The specified chloropyridazone 32,5; the specified thiol-carbamate 20; sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde 4,5; synthetic silicic acid 1.5; said block copolymer 2, water 39.2, wherein the weight ratio of said chloropyridazone and thiol carbamate is 1.625: 1.
    This suspension is transferred to a 2% aqueous preparation that is stored at BOC for 3 months. A formation of 0.09 ml of bottom sediment is observed.
    B. According to the known. Example 2A is repeated, with the difference that phenyl-4-amino-5-chloropyridazone-Sb) and N, N-diisopropylthiolcarbamic acid 2,3,3-triallyl ester are dissolved in a weight ratio of 1: 2.5, At the same time, after storing the 2% aqueous preparation at 50 ° C for 3 months, 8.8 ml of bottom sediment is observed.
    Prima RZ, A, Offered (T11 option),
    Example 1A is repeated with the difference that 333 g of N-ethyl-N ethyl ester are added to 672 MP of an aqueous suspension containing 289 g of 1-phenyl-4-amino-5-chloro-1 cross; zone- (b). -cyclohexylthiolcarbamic acid and distilled water are added to 1000 ml. When this receive a suspension containing, wt.%: The specified chloropyridazone 28.9 specified thiolcarbamate 33,3; sodium salt of condensation product phenol sulfonic acid, urea and formaldehyde 4; synthetic silicic acid l, 3j indicated block copolymer 2; water 30.5, with the indicated chloropyridazone and thiol carbamate taken in a mass ratio of 1: 1.15,
    This suspension is transferred to a 2% aqueous preparation which is stored at room temperature for 24 hours. A formation of 0.05 ml of bottom sediment is observed,
    B, According to the famous. Example 3a is repeated, with the difference that 1-phenyl-4-amino-5-tslorpiridazon- (b and specified
    602
     the thiocarboxylic acid derivative is used in a mass ratio of 1: 2.5. At the same time, after storage of a 2% aqueous preparation with
    5 room temperature for
    24 hours, 4.8 ml of bottom sediment is observed.
    PRI me R 4. Proposed (GTG option). Repeat the example FOR
    0 with the difference that to 549 ml of the aqueous suspension of Example 1A, containing 236 g-t |) enyl-4-amino-5-chloropyridazone- (b), 364 g of N-ethyl ethyl ester ester are added. N-cyclo
    ) 5 hexylthiolcarbamic acid and distilled water were added to 1000 ml.
    A suspension is obtained containing, in wt%: the indicated chloropyridazone 23.6;
    20 specified thiolcarbamate 36.4; and the salt of the said condensation product is 3.3; synthetic silicic acid 1.1; the specified block copolymer of 1.65; water 33.95, with the indicated chlorpyridazone and thiol carbamate taken in a weight ratio G: 1.54,
    This suspension is transferred to a 2% aqueous preparation which is stored at room temperature for 24 hours. The formation of O, 1 ml of bottom sediment is observed.
    Example5, A, Proposed 1U optionJ.
    Example 1A is repeated, with the difference that 187.5 g of 2-ethyl-6-methyl- is added to 756 ml of an aqueous suspension containing 325 g of 1-fensch-1-4-amio-5-chloro-pyridazone- (b) M-ethyl-M- (1-methyl-2-methoxyethyl) chloroacetate O nilide and distilled water are added to 1000 ml. Get the suspension containing, wt.%: The specified chloropyridazone 32,5; the specified chloroacetanilide 18,7; sodium
     salt of the specified condensation product 4,5; synthetic silicic acid 1.5; the specified block-copoly-: measure 2,3; water is 40.5, and the specified chloropyridazone and chloroacetanilide are taken at a mass ratio of 1.73: 1,
    This suspension is transferred to a 2% aqueous preparation which is stored at room temperature for 24 hours. A formation of 0.04 ml is observed.
    55 bottom sediment,
    B. According to the known. Example 5A is repeated with the same 1-step that the specified prozzodnye pi0
    readazone- (b) and chloroacetanilide are used in a mass ratio of 1: 2.5. After storage of 2% water of a lioro preparation at room temperature for 6 hours, 6 ml of a water precipitate is observed.
    Example 6. A. The proposed () Y option).
    Example 1A is repeated with the difference that 333 g of 2-ethyl-6-methyl is added to 505 ml of an aqueous suspension containing 216 g of 1-t | enyl-4-amino-5-chloropyridazone (6) The -N- (l-methyl-2-methoxyztil) -chloroethanedanilide and distilled water are added to 1000 ml.
    A suspension is obtained containing, in wt.%: The indicated; chloropyridazone 21.6, the indicated chloroacetanilide 33.3; sodium salt of the specified condensation product 3; synthetic silicic acid 1; the specified block copolymer of 1.5; water is 39.6, and the indicated chloropyridazone and chloroacetanide are taken in a mass ratio of 1: 1.54. This suspension is transferred to a 2% aqueous preparation which is stored at room temperature for 24 hours. At the same time, a formation of 0.1 ml of bottom sediment is observed.
    B. According to the known.
    Example 6A is repeated, with the difference that said chloropyridazone and chloroacetanilide are used in a mass ratio of 1: 2.5. At the same time, after storing the 2% aqueous preparation at room temperature for 24 hours, 4.5 ml of bottom sediment is observed.
    Example 7.A. Offered (V variant),
    Example 1A is repeated, with the difference that to 498 ml of an aqueous suspension containing 214 g of 1-phenyl-4-amino-5-bromo-pyridazone- (6), 214 g of 2,6-dinitro-3,4- dimethyl-N- (l-ethyl-n-propyl) -aniline and supplemented with distilled water to 1000 ml.
    Get the suspension containing, wt.%: The specified bromopyridazone 21.4 specified aniline 21,4; sodium salt of the specified condensation product 3; synthetic silicon, acid 1; the specified block copolymer of 1.5; water 51.7; wherein said bromopyrchdazone and aniline are taken in a 1: 1 mass ratio.
    ten
    t5
    0
    five
    0
    five
    0
    five
    This suspension is transferred to a 2% aqueous preparation, which is stored at room temperature for 24 hours. At the same time, O, 1 ml of bottom sediment is formed.
    B. According to the known.
    Example 7A is repeated, with the difference that the pyridazone and aniline derivatives are used in a mass ratio of 1: 2.5. At the same time, after storing the 2% aqueous preparation at room temperature for 24 hours, 4.8 ml of bottom sediment is observed.
    Sample (t option),
    Example 1A is repeated, with the difference that an aqueous suspension is prepared containing, in wt%: 1-phenyl-4-amino-5-chloropyridazone- (6) 20; GG71-diisopropylthiol-carbamic acid 2,3-2,3-dichloroallyl ester; sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde 2; synthetic silicic acid 0.5; the specified block copolymer of 0.5; water 37. At the same time, the mass ratio of said chlorpyridazone and thiol carbamate is 1: 2.
    Example9 (1 option).
    Example 1A is repeated, with the difference that an aqueous suspension is prepared containing, in wt%: 1-phenyl-4-amino-5-chloropyridazone- (b) 50; 2,3, dichloroallyl ester of M, N-diisopropylthiolcarbamic acid 12.5; sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde 5; synthetic silicon wa acid 5; said block copolymer 5; water 22.5. The mass ratio of these chloropyridazone and thiol-carbamate is 4: 1.
    Example 10 (T option).
    Example 1A is repeated, with the difference that an aqueous suspension is prepared containing, in wt%: 1-phenyl-4-amino 5-chloropyridazone (b) 25; N, N-diisopropylthiolcarbamic acid 45,3-dichloropropyl ester; sodium salt of the specified condensation product 5; synthetic - silicic acid 0.5; indicated block copolymer 0.5; water is 24. In this case, the weight ratio of said chloropyridazone and thiol carbamate is 1: 1.8.
    Example 1A: Example 1A is repeated, with the difference that an aqueous suspension is prepared containing, in May,%: 1-1-A-amino-5-chloropyrzone 20; 2,3-dichloroallyl ester of H jN-diisopropylthioL-carbamic acid 5; sodium salt of the said condensation product lOj synthetic silicic acid 2; said block copolymer 2; water 61. At the same time, the mass ratio of said chloropirvdazone and thiol carbamate is 4: 1.
    Data on the stability of the suspension in the form of an aqueous preparation at room temperature for 24 hours in examples 9–11 are given in table i,
    V.
    Data on the herbicidal activity of suspensions in example 1-11 are given in tal2.
    These data were obtained after tillage before seeding the plant suspension 1 with water suspension. Experiments were carried out in open ground.
    Table 1.
    Suspension by Example
    The stability of the suspension at room temperature for 24 h, the formation of bottom sediment, ml
    X
     repetition of the relevant experience in the application of active substances in the ratio of 1: 2.5 (according to the prototype); repetition of the relevant experience in the application of active substances in the ratio of 5: 1 (according to the prototype)}
    Table 2
     - suspension of Example 9 containing the active substance in a ratio of 5: 1;
    S -.
    - suspension of example 11 containing the active substance in a 5: 1 ratio,
    Editor N.Kishtulinets
    Compiled by N.Golubeva Tehred T.Tulik
    Order 914/62 Circulation 679
    VNSHPI USSR State Committee
    for inventions and discoveries 113035, Moscow, Raushsk nab., 4/5
    Branch PPP Patent, Uzhgorod, Proektna St., 4
    Corrector V. But ha
    Subscription
    权利要求:
    Claims (5)
    [1]
    1. Suspension for combating unwanted vegetation, containing an active substance based on pyridazone - ^ (b), a dispersant - the sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde, stabilizers - silicic acid and a block copolymer with an average molecular weight of 6500 based on a polyoxypropylene block having an average molecular weight of 3250, and blocks of ethylene oxide and water symmetrically attached to it, characterized in that, in order to increase storage stability, it is an active substance with holds a mixture of 1-phenyl-4-amino-5-chloro; pyridone azona- (6) with 2,3-dichlorallyl ester of Ν, Ν-diisopropylthiol carbamic acid in the following ratio of components, wt.%:
    1-Phenyl-4-amino-5chloro-pyridazone- (6) 20-50
    [2]
    2,3, Ν, Ν-diisopropyl · thiolcarbamic acid dichlorallyl ether
    The sodium salt of the condensation product of phenolsulfonic acid, urea and silicon-formaldehyde.
    Eva Acid Indicated
    5-45
    2-10
    0.5-5 block copolymer Water wherein said
    0.5-5
    The rest, pyridazine and ether are taken in a mass ratio of 4: 1-1: 2,
    2. Suspension for combating undesirable vegetation containing an active substance based on pyridazone- (b), a dispersant — the sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde, stabilizers — silicic acid and a block copolymer with an average molecular weight of 6500 based on a polyoxypropylene block having an average molecular weight of 3250, and ethylene oxide blocks and water symmetrically attached thereto, characterized in that, in order to increase storage stability, it is an active substance contains a mixture of 1-phenylamino-5-chloro-pyridone-azone- (6) with N, Ν diisopropylthiolcarbamic acid 2,3,3-triallyl ester in the following ratio, May.%:
    SU „„ 1215602
    1 — Phenyl — 4 — amino-5-chloro-pyridazone- (6) 32.5
    2,3, Ν, Ν-diisopropylthiolcarbamic acid 3-triallyl ester
    Sodium salt of the product of the condensation of phenolsulfonic acid of erythra, urea and formaldehyde
    Silicic> Acid
    The specified block copolymer
    Water
    four.
    20,0
    4.5
    1.5
    2,3
    Rest
    [3]
    3. Suspension for combating undesirable vegetation, containing an active substance based on pyridazone- (b), a dispersant - the sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde, stabilizers - silicic acid and a block copolymer with an average molecular weight of 6500 based on polyoxypropylene a block having an average molecular weight of 3250, and ethylene oxide blocks and water symmetrically attached thereto, characterized in that, in order to increase storage stability, it is an active substance win mixture of 1-phenyl-4-amino-5-chloro-piriddzona- (b) with ethyl N-ethyl-N-cyclo- geksiltiolkarbaminovby acid with the following ratio of components, mass%.:
    1 — Phenyl — 4-amino-5chloro — pyridazone-6 Said thiol carbamate
    Sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde
    Silicic acid
    Specified block copolymer Water
    23.6-28.9
    33.3-36.4
    3.3-4.0
    1.1-1.3
    1.65-2.0
    The rest, with the indicated pyridazone and ether taken in a mass ratio of 1: (1,151.54).
    [4]
    4. Suspension for the control of undesirable vegetation, containing an active substance based on pyridazone- (b), a dispersant — the sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde, stabilizers — silicic acid and a block copolymer with an average molecular weight of 6500 based on a polyoxypropylene block having an average molecular weight of 3250, and ethylene oxide blocks and water symmetrically attached thereto, characterized in that, in order to increase storage stability, it is used as an active substance a contains a mixture of 1-phenyl-4amino-5-chloro-pyridazone- (b) with 2ethyl-b-methyl-H-ethyl-N- (1-methyl-2methoxyethyl) -chloroacetanilide in the following ratio, wt.%:
    1 — Phenyl — 4-amino— 5 — chlorine — pyridazone- (6) 21.6-32.5 Specified chloroacetanil id 18.7-33.3 Sodium wow. salt (product phenol condensation sulfo acid urea and formalde guide 3.0-4.5 Silicon acid 1.0-1.5 The specified block is copolymer 1.5-2.3 Water Rest
    moreover, the indicated pyridazone and chlorine-acetanilide are taken in a mass ratio of 1.73: 1 or 1: 1.54.
    [5]
    5. Suspension for combating unwanted vegetation, containing the active substance based on pyridazone- (b)) the dispersant is the sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde, the stabilizers are silicic acid and a block copolymer with an average molecular weight of 6500 based on a polyoxypropylene block, having an average molecular weight of 3250, and ethylene oxide blocks symmetrically attached to it, and water, characterized in that, in order to increase storage stability, it is an active substance with holds a mixture of 1 — phenyl— 4-amino — 5-bromo-pyridazone— (6) with 2,61215602 dinitro — 3,4 — dimethyl — Ν— (1 — ethyl — n— · propyl - aniline in the following ratio of components, wt .%:
    1-phenyl — 4 — amino—
    5-bromo-pyridazone- (6)
    21,4
    The specified 2,6-di- ·; · nitro-aniline
    21,4
    Sodium salt of the condensation product of phenolsulfonic acid, urea and formaldehyde Silicic acid
    Specified block copolymer
    Water
    3.0
    1,0
    1,0
    Rest
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    同族专利:
    公开号 | 公开日
    FI800665A|1980-09-09|
    CS212342B2|1982-03-26|
    DK98380A|1980-09-09|
    BG40473A3|1986-12-15|
    FI65888C|1984-08-10|
    CA1138216A|1982-12-28|
    DK154801C|1989-05-16|
    GR69631B|1982-07-06|
    PL121889B2|1982-06-30|
    IL59470A|1984-01-31|
    HU188321B|1986-04-28|
    IE49543B1|1985-10-30|
    ES8200004A1|1981-10-16|
    EP0017001B1|1982-04-28|
    DE3060319D1|1982-06-09|
    ES489319A0|1981-10-16|
    US4305750A|1981-12-15|
    PT70953A|1980-04-01|
    FI65888B|1984-04-30|
    PL123429B2|1982-10-30|
    DE2909158A1|1980-09-11|
    IL59470D0|1980-05-30|
    EP0017001A1|1980-10-15|
    AT900T|1982-05-15|
    IE800457L|1980-09-08|
    DD149894A5|1981-08-05|
    AR222857A1|1981-06-30|
    DK154801B|1988-12-27|
    MA18766A1|1980-10-01|
    PL222504A1|1980-12-01|
    JPS55122704A|1980-09-20|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US3210353A|1958-11-21|1965-10-05|Basf Ag|Substituted pyridazones|
    US3330821A|1959-05-06|1967-07-11|Monsanto Co|Certain thiolcarbamate compounds|
    DE1921464A1|1969-04-26|1970-12-17|Basf Ag|herbicide|
    US3862832A|1969-10-23|1975-01-28|Adolf Fischer|Herbicidal mixture of thioalkyl carbamates and 1-phenyl-4-amino-5-halopyridazone- or salts thereof|
    DE2219922A1|1972-04-22|1973-10-31|Basf Ag|METHOD OF CONTROL OF UNWANTED PLANTS|
    US3937730A|1972-06-06|1976-02-10|Ciba-Geigy Corporation|Plant growth regulating agent|
    DE2334563A1|1973-07-07|1975-01-30|Basf Ag|HERBICIDE|
    NO743390L|1973-10-15|1975-05-12|Basf Ag|
    DE2412270A1|1974-03-14|1975-09-25|Basf Ag|HERBICIDE|
    DE2453255C3|1974-11-09|1981-08-13|Basf Ag, 6700 Ludwigshafen|Herbicidal suspension based on 1-phenyl-4-amino-5-halogen-pyridazon- |
    DE2547968A1|1975-10-27|1977-05-05|Basf Ag|HERBICIDE|US3794960A|1972-11-30|1974-02-26|Itt|Junction shell|
    HU184467B|1981-07-08|1984-08-28|Eszakmagyar Vegyimuevek|Herbicide composition containing the mixture of two active agents|
    DE3302648A1|1983-01-27|1984-08-02|Hoechst Ag, 6230 Frankfurt|PLANT PROTECTION AGENT IN THE FORM OF MIXED DISPERSIONS|
    DE3631558A1|1986-09-17|1988-03-31|Hoechst Ag|NEW SUSPOEMULSIONS OF PLANT PROTECTION ACTIVE INGREDIENTS|
    GB8710105D0|1987-04-29|1987-06-03|Ici Plc|Pesticidal formulations|
    US5731266A|1993-03-17|1998-03-24|Ciba-Geigy Corporation|Herbicidal compositions comprising diamino-1,3,5-triazine and chloroacetanilide herbicides and a surfactant system|
    DE4322211A1|1993-07-03|1995-01-12|Basf Ag|Aqueous, multi-phase, stable ready-to-use formulation for crop protection agents and processes for their preparation|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    DE19792909158|DE2909158A1|1979-03-08|1979-03-08|HERBICIDAL MIXTURES|
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